The status, kinds and properties of the catalysts for oxidative coupling of methane to C_2 compounds were reviewed. 本文详细地介绍了甲烷氧化偶联制备C2的催化剂研究概况,并着重分忻了催化剂的种类及其特性。
Research on Computer-Aided Catalyst Design and an Application in Multi-Component Catalyst Design of Methane Oxidative Coupling 计算机辅助催化剂配方优选及在多组分甲烷氧化偶联催化剂设计中应用
Beckman SO2 analyzer PVP-Capped Silver Nanoparticles as Catalyst for Oxidative Coupling of Thiols to Disulfides 纳米银催化氧化偶联硫醇制二硫化物
Preparation of M-W-Mn/ SiO_2/ cordierite monolithic catalysts and their performances for oxidative coupling of methane M-Mn-W/SiO2/堇青石整体式催化剂及其甲烷氧化偶联反应性能
A Study of Catalytic Properties of Doped SrTiO_3 Catalysts for Oxidative Coupling of Methane 掺杂SrTiO3体系上甲烷氧化偶联催化性能的研究
The oxidative coupling of methane and the effect of applied current on it were studied in a solid oxide electrolyte membrane reactor ( Ag| YSZ| Ag). A reaction network was also proposed. 研究了固体氧化物电解质膜反应器(AgYSZAg)中甲烷氧化偶合动力学和外加电流对反应结果的影响,提出了该反应系统中甲烷偶合反应网络。
The first total synthesis of 1a,(±)-2 and(±)-3 was described and the oxidative coupling yield of synthesis of(±)-1 was higher than that in literatures. 首次完成了1a,(±)-2和(±)-3的全合成,并以较文献报道为高的氧化偶联产率合成了(±)-1。
Study on the Laser Stimulated Surface Reaction of Oxidative Coupling of Methane 激光促进甲烷氧化偶联表面反应规律的研究
The structure and physical chemistry properties of these catalysts were characterized by XRD, XPS, BET, O_2-TPD and CO_2-TPD techniques, and their catalytic performances for the oxidative coupling of methane ( OCM) were evaluated in a continuous micro-reactor. 用XRD、XPS、BET、O2-TPD和CO2-TPD等方法对催化剂进行了表征,并考察了对甲烷氧化偶联反应的催化性能。
In this paper kinetics of the oxidative coupling of methane over CaO-Li-CeO_2 catalysts is reported. 本文报导在CaO-Li-CeO2催化剂上甲烷氧化偶联反应的宏观动力学。
A kinetic study on the oxidative coupling of methane over the Li-Mn-Ti-O catalyst has been carried out, and a supposed reaction mechanism is suggested. 对复合氧化物Li-Mn-Ti-O催化剂上的甲烷氧化偶联反应进行了动力学研究,提出了一个可能机理。
Study on heat effect of methane oxidative coupling in the thin layer reactor 薄层固定床反应器中甲烷氧化偶联反应热效应的研究
In this paper, the catalytic mechanism of La 2O 3 for the oxidation of methane and the oxidative coupling of methane were studied. 本文研究了La2O3对CH4氧化燃烧和氧化偶联的催化机制。
The performance of PbO/ y-Al2O3 catalyst for the oxidative coupling of methane was studied from the point of view of metallic oxide-support interaction by catalytic evaluation, and XPS and XRD measurements. 从金属氧化物-担体相互作用观点研究了PbO/γ-Al2O3催化剂上甲烷氧化偶联的反应特性,进行了反应评价及XPS和XRD测定。
Li-Fe and Li-Ni oxide catalysts were used for catalytic oxidative coupling of methane. 在不同原子比的Li-Nj、Li-Fe氧化物催化剂上进行甲烷氧化偶联反应机理的研究。
The Role of Lattice and Gaseous Oxygen on the Oxidative Coupling of Methane Studied by a Pulse Reaction Technique 脉冲反应技术研究气相氧和晶格氧对甲烷氧化偶联的作用
Unctions of oxide catalysts containing La series elements in the methane oxidative coupling reaction have been investigated. 对La系元素氧化物催化剂在甲烷氧化偶联反应中的作用进行了研究。
The Mechanism of Oxidative Coupling of Methane on a-LiFeO_2, LiNiO_2 在LiFeO2、LiNiO2上甲烷氧化偶联机理的研究
Study of oxidative coupling of methane to ethylene I.Investigation on the activity of SnO_2 catalyst 甲烷氧化偶联制乙烯的研究I.SnO2催化剂的活性考察
Effect of rare earth oxides on catalytic oxidative coupling of methane on Li-ALKALINE earth oxide 稀土氧化物对甲烷在Li-碱土金属氧化物催化剂上氧化偶联反应的影响
The influence that w containing in the catalysts with various degrees acts on the methane oxidative coupling action which takes na-w-mn/ sio2 as catalysts, has been analyzed with the fuzzy cluster analysis. 应用模糊聚类分析的方法分析在以Na-w-Mn/SiO2为催化剂的甲烷氧化偶联反应中w的不同含量对反应的影响。
The promoter effects of Li, La, Mn and W on the catalytiC properties of TiO2-based catalysts in the oxidative coupling of methane have been studied. 研究了在以TiO2为基础的甲烷氧化偶联催化剂中添加Li、La、Mn、W等对催化剂性能的影响。
In this paper, the catalytic properties of a series of CaO/ La2O3 catalysts for oxidative coupling of methane have been studied. 研究了不同配比的CaO/La2O3催化剂对甲烷氧化偶联反应的催化性能。
Effect of some sodium salts on licl/ sio_2 catalyst in the oxidative coupling of methane 钠盐对甲烷氧化偶联LiCl/SiO2催化剂的影响
The effect of pH values, metal ions on the structures of complexes was analysed. Furthermore, the relationship between structures and catalytic properties was also discussed, and a plausible reaction mechanism for the present oxidative coupling reaction was proposed. 2. 同时分析了pH值、金属离子对聚合物结构的影响,并讨论了结构与催化性能之间的关系,推测了可能的催化反应机理。
The development of new high activity catalyst and reaction process has been to the priority and difficulty for oxidative coupling of methane. 开发新型和高活性的催化剂及反应工艺一直是甲烷氧化偶联反应研究的重点和难点。
Recently, the oxidative coupling reaction provides a convenient method for the synthesis of organic amines. 近年开发的C-C键氧化偶联反应,提供了一条合成有机胺的简便途径。
This thesis describes my graduate study which involves applying the oxidative coupling reactions to the synthesis of N-heterocycles Compounds in the organic synthesis. 本论文主要对氧化偶联反应在含氮杂环化合物合成中的应用做了研究,论文分为三章。
In this thesis, chiral amine-ligands were synthesized from cheap and commercially available chiral source. The applications in asymmetric oxidative coupling reaction were initially explored. 本论文利用便宜、易得的手性源设计合成了系列的手性胺配体,对其在不对称催化氧化偶联反应中进行了初步的研究。
Based on the research of literatures and experimental data, a mechanism of free radical oxidative coupling reaction was proposed. And the radical annihilation experiments were designed to validate the mechanism. 在文献调研和实验数据基础上,提出了自由基氧化偶联反应机理,并设计了自由基湮灭实验进行了验证,初步确定了该反应的自由基历程。